Kinetics of oxidation of benzyl alcohol and substituted benzyl alcohols by N-chlorosaccharin was written by Vijaya Mohan, K.;Rao, P. Raghunatha;Sundaram, E. V.. And the article was included in Proceedings of the National Academy of Sciences, India, Section A: Physical Sciences in 1988.Computed Properties of C7H4ClNO3S This article mentions the following:
The acid catalyzed oxidation of benzyl alcs. by N-chlorosaccharin was studied in aqueous AcOH medium in the presence of saccharin. The reaction is first-order with respect to [substrate] and [oxidant]. A plot of log kobs vs. ρ is linear with σ = -3.07. The rate is not affected by added Cl–. Bunnett’s plot shows that water mols. act as proton transfer agents in the rate determining step. In the experiment, the researchers used many compounds, for example, 2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide (cas: 14070-51-0Computed Properties of C7H4ClNO3S).
2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide (cas: 14070-51-0) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.Computed Properties of C7H4ClNO3S
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics