One-pot synthesis of N,N-dimethylanilines from nitroarenes with skeletal Cu as chemoselective catalyst was written by Rong, Zeming;Zhang, Wenjun;Zhang, Peng;Sun, Zhuohua;Lv, Jinkun;Du, Wenqiang;Wang, Yue. And the article was included in Catalysis Communications in 2013.Electric Literature of C8H10ClN This article mentions the following:
A range of N,N-dimethylanilines were synthesized with excellent yields in one-pot by the hydrogenation and alkylation of nitro arenes with H2 and CH2O over quenched skeletal Cu catalyst, which provides a facile, economical, and environmentally benign alternative methodol. for C-N bonds formation. In the experiment, the researchers used many compounds, for example, 2-Chloro-N,N-dimethylaniline (cas: 698-01-1Electric Literature of C8H10ClN).
2-Chloro-N,N-dimethylaniline (cas: 698-01-1) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Electric Literature of C8H10ClN
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics