Mechanism of oxidation of some active methylene compounds by N-chlorosaccharin in acetic acid-water medium. A kinetic study was written by Khan, M. U.;Nigam, S. K.;Gupta, O. P.;Tiwari, A. K. S.;Parihar, S. S.;Nigam, A.. And the article was included in Oxidation Communications in 1999.Related Products of 14070-51-0 This article mentions the following:
Oxidation of MeCOCH2CO2Et and CH2(CO2Et)2 by N-chlorosaccharin in aqueous AcOH was studied. This reaction exhibits 1st-order dependence on both [oxidant] and [substrate]. The reaction is acid catalyzed. The effect of solvent on the reaction kinetics was also examined, as was the effect of ionic strength of the medium. The reaction rate was retarded by the addition of saccharin. The stoichiometry of the oxidation is 1:2, which shows the formation of a transitory complex between the enolic form of the substrate and the oxidant. The effect of temperature on reaction rate was also studied, and the thermodn. parameters were evaluated. Taking into account all the observed kinetic data, a plausible mechanism was described and a suitable rate law was derived. In the experiment, the researchers used many compounds, for example, 2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide (cas: 14070-51-0Related Products of 14070-51-0).
2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide (cas: 14070-51-0) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.Related Products of 14070-51-0
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics