Late 3d-Transition Metal Complexes Bearing a Bis-Phosphine Borane Ligand, PhB(CH2PtBu2)2 was written by Handford, Rex C.;Zhong, Lingfei;Tilley, T. Don. And the article was included in Organometallics in 2022.Name: (Chloromethanetriyl)tribenzene This article mentions the following:
The coordination chem. of a bidentate ambiphilic ligand, PhB(CH2PtBu2)2 ([BP2tBu]), is established for a series of Co, Ni, and Cu compounds The chloride starting materials [BP2tBu]MCl2 [M = Co (1Co), Ni (1Ni)] and [BP2tBu]CuCl (2Cu) are readily accessed in high yields by the treatment of the corresponding metal chloride salts with [BP2tBu] in THF solution The reduction of 1Ni to [BP2tBu]NiCl (2Ni) was affected by treatment with KC8. In contrast, the corresponding CoI species was not isolable under similar reaction conditions. However, monovalent mesityl complexes of the form [BP2tBu]M(Mes) [M = Co (3Co), Ni (3Ni), Cu (3Cu)] were prepared by the treatment of 1Co with one equiv of Mes2Mg(THF)2 or by the reaction of 2M (M = Ni, Cu) with 0.5 equiv of Mes2Mg(THF)2. Modification of the borane moiety in 2Ni was explored by the treatment of this complex with 4-dimethylaminopyridine (DMAP) to produce [PhB(DMAP)(CH2PtBu2)2]NiCl (4), which displays distinct features in its UV-visible spectrum compared to 2Ni. The solid-state mol. structures of most complexes have been determined by single-crystal X-ray diffraction anal. In the experiment, the researchers used many compounds, for example, (Chloromethanetriyl)tribenzene (cas: 76-83-5Name: (Chloromethanetriyl)tribenzene).
(Chloromethanetriyl)tribenzene (cas: 76-83-5) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.Name: (Chloromethanetriyl)tribenzene
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Chloride – Wikipedia,
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