Kinetics of oxidation of some amino acids by N-chlorosaccharin in aqueous acetic acid medium was written by Farook, N. A. Mohamed;Prabaharan, R.;Rahini, S.;Kumar, R. Senthil;Rajamahendran, G.;Krishnan, B. Gopala. And the article was included in E-Journal of Chemistry in 2004.Reference of 14070-51-0 This article mentions the following:
The kinetics of oxidation of some amino acids (AA; glycine, alanine, aspartic acid, arginine, and histidine) by N-chlorosaccharin (NCSA) has been studied in aqueous acetic acid medium in the presence of perchloric acid. The observed rate of oxidation is first order in [AA], [NCSA] and of inverse fractional order in [H+]. The main product of the oxidation is the corresponding aldehyde. The ionic strength has no significant effect on the reaction rate. The effect of changing the dielec. constant of the medium on the rate indicates the reaction to be of dipole-dipole type. Hypochlorous acid has been postulated as the reactive oxidizing species. Activation parameters are computed with respect to slow step of the mechanism. In the experiment, the researchers used many compounds, for example, 2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide (cas: 14070-51-0Reference of 14070-51-0).
2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide (cas: 14070-51-0) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Reference of 14070-51-0
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics