Platinum-catalyzed hydrosilylation of allyl aryl ethers: kinetic investigation at moderately high dilution was written by Coqueret, Xavier;Wegner, Gerhard. And the article was included in Organometallics in 1991.Related Products of 12083-92-0 This article mentions the following:
A kinetic investigation of the platinum-catalyzed hydrosilylation of some allyl aryl ethers by dimethylsilyl end groups of a monofunctional model oligomer or of a telechelic poly(dimethylsiloxane) was performed with use of quant. IR spectrophotometry. The reactivity of (allyloxy)benzene (I), examined at low inital concentration of reactants in toluene (ca. 10-2 equiv·L-1), with dichloro(dicyclopentadiene)platinum(II) as a precursor of the catalyst was found to be different from the reactivity of the allylic groups of 3,5-(CH2:CHCH2O)2C6H3CO2Me (II). The reaction rate can be expressed by v(I) = k3[Pt][Si-H]2 in the case of reactions with I and by v(II) = k4[Pt]2[Si-H]2 for reactions with II. In addition to the determination of the values of the phenomenol. rate constants deduced from measurements carried out under mild conditions, the obtained results lead to the proposal of some special features for the effective catalytic process. In the experiment, the researchers used many compounds, for example, Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0Related Products of 12083-92-0).
Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Related Products of 12083-92-0
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics