Kinetics and mechanism of oxidation of diethylene glycol by N-chlorosaccharin in cetyltrimethylammonium bromide catalyzed system was written by Sharma, Vandana;Sharma, K. V.;Bhagwat, V. W.. And the article was included in Physical Chemistry: An Indian Journal in 2007.Quality Control of 2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide This article mentions the following:
The kinetics and mechanism of Cetyltrimethylammonium bromide catalyzed oxidation of diethylene glycol [2,2′-oxydiethanol] by N-chlorosaccharin in aqueous acetic acid medium in presence of perchloric acid have been investigated at 318-338 K temperature range. The reaction has first order dependence on N-chlorosaccharin concentration The reaction rate follows fractional order kinetics with respect to [diethylene glycol] with excess concentration of other reactants. The micelle effect due to Cetyltrimethylammonium bromide- a cationic surfactant has been studied. The change in ionic strength shows negligible salt effect. The dielec. effect is found to be pos. Addition of one of the product saccharin retards the reaction rate. Activation parameters are calculated from the Arrhenious plot. A possible mechanism consistent with the exptl. results has been proposed. In the experiment, the researchers used many compounds, for example, 2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide (cas: 14070-51-0Quality Control of 2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide).
2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide (cas: 14070-51-0) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Quality Control of 2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics