Linear relations between thermodynamic parameters. III. Application to solvolysis reactions was written by Lee, Ikchoon. And the article was included in Taehan Hwahakhoe Chi in 1963.Safety of 2-Chloro-N,N-dimethylaniline This article mentions the following:
The general equation for the test of the substituent effect which was derived in the previous paper was extended to correlate thermodn. parameters of solvolysis reactions by modifying the potential energy term to represent the effect of change in solvent composition The linear fits of the new equation, ΔΔH.dbldag. = a’Y + bΔΔS=, were tested with 35 examples taken from the literature and an average correlation coefficient of 0.977 was obtained. The equation is generally applicable to solvolysis reactions and helps elucidate some of the difficulties experienced with the Grunwald-Winstein equation (CA 42, 8591a). The linear enthalpy-entropy effect exists only between the external enthalpy and entropy of activation. In the experiment, the researchers used many compounds, for example, 2-Chloro-N,N-dimethylaniline (cas: 698-01-1Safety of 2-Chloro-N,N-dimethylaniline).
2-Chloro-N,N-dimethylaniline (cas: 698-01-1) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.Safety of 2-Chloro-N,N-dimethylaniline
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics