Methylation of aniline and its derivatives with dimethyl carbonate in the presence of binder-free micro-, meso-, and macroporous zeolites KNaX, NaY, and HY was written by Khusnutdinov, R. I.;Shchadneva, N. A.;Mayakova, Yu. Yu.;Ardieva, S. I.;Khazipova, A. N.;Kutepov, B. I.. And the article was included in Russian Journal of Organic Chemistry in 2016.Recommanded Product: 2-Chloro-N,N-dimethylaniline This article mentions the following:
Aniline and its derivatives RC6H4NH2 (R = H, 3-CH3, 4-Br, etc.) which undergo methylation when treated with di-Me carbonate in the presence of binder-free micro-, meso-, and macroporous zeolites KNaX, NaY, and HY and leads to the formation of N-methyl- and N,N-dimethylanilines RC6H4NHCH3, RC6H4N(CH3)2 have been described. In the experiment, the researchers used many compounds, for example, 2-Chloro-N,N-dimethylaniline (cas: 698-01-1Recommanded Product: 2-Chloro-N,N-dimethylaniline).
2-Chloro-N,N-dimethylaniline (cas: 698-01-1) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.Recommanded Product: 2-Chloro-N,N-dimethylaniline
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics