Kinetic and mechanistic investigation of N-chlorosaccharin oxidation of 2-alkanones was written by Khan, Shahnaz;Khan, M. U.;Singh, Sanjay Kumar;Gupta, H. D.;Singh, P. K.. And the article was included in Asian Journal of Chemistry in 2003.Recommanded Product: 14070-51-0 This article mentions the following:
N-Chlorosaccharin (NCSA) oxidation of 2-alkanones is studied in aqueous acetic acid and perchloric acid medium. The reactions exhibit first order dependence in oxidant [NCSA]. The order of the reactions with respect to substrate and perchloric acid varies from one to zero. The reaction velocity retards by the addition of saccharin and rising percentage of binary mixture of acetic acid and water whereas primary salt shows slightly increasing trends in kinetic rate. The stoichiometric studies revealed 1:2 mol ratio with complex mechanism. In the experiment, the researchers used many compounds, for example, 2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide (cas: 14070-51-0Recommanded Product: 14070-51-0).
2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide (cas: 14070-51-0) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.Recommanded Product: 14070-51-0
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics