Preparation of acyloxymethyl halides from acylals was written by Grynkiewicz, Grzegorz;Tsien, Roger Y.. And the article was included in Polish Journal of Chemistry in 1987.Recommanded Product: 5335-05-7 This article mentions the following:
Reaction of CH2(OAc)2 with Me3SiBr in the presence of ZnCl2 gave 81% AcOCH2Br. Similarly, CH2(OBz)2 was treated with Me3SiR (R = Br, Cl) and ZnCl2 or AlCl3 to give 50 and 21%, resp., of BzOCH2R. In contrast, cleavage of MeOCH2OAc with Me3SiBr gave MeOCH2Br and AcOIMe3. In the experiment, the researchers used many compounds, for example, Chloromethyl benzoate (cas: 5335-05-7Recommanded Product: 5335-05-7).
Chloromethyl benzoate (cas: 5335-05-7) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Recommanded Product: 5335-05-7
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics