Preparations of chloro(diene)polyfluorophenylplatinum(II) complexes and the structure of chloro(dicyclopentadiene)pentafluorophenylplatinum(II) was written by Deacon, G. B.;Gatehouse, B. M.;Nelson-Reed, K. T.. And the article was included in Journal of Organometallic Chemistry in 1989.HPLC of Formula: 12083-92-0 This article mentions the following:
The complexes, PtCl(diene)R [diene = hexa-1,5-diene (hex), norbornadiene (nbd), R = C6F5, p-HC6F4, p-MeOC6F4; diene = dicyclopentadiene (dcy), R = C6F5] have been prepared by reaction between equimolar amounts of PtCl2(diene) and Me3SnR in CH2Cl2. Most reactions also gave some of the corresponding PtR2(diene) complex, which was readily separated by chromatog., and Pt(p-MeOC6F4)2(nbd) was obtained in high yield from PtCl2(nbd) and Me3Sn(p-MeOC6F4) when a 1:2 mol ratio was used. Attempts to prepare PtCl(dcy)R (R = p-HC6F4, p-MeOC6F4) from Me3SnR gave only PtR2(dcy) in boiling CH2Cl2 despite the use of 1:1 reactant stoichiometry, and Pt(p-MeOC6F4)2(dcy) or no reaction (R = p-HC6F4) at room temperature Alternative reagents, R’3SnR (R’ = Bu, Et; R = C6F5, p-MeOC6F4) had a variable effect on the selectivity of monoarylation. Thus, Bu3SnC6F5 was more selective and Et3SnC6F5 less selective in formation of PtCl(hex)C6F5 than Me3SnC6F5. With Et3SnR (R = C6F5, p-MeOC6F4) and an equimolar amount of PtCl2(dcy), PtCl(dcy)R was the major product. The crystal structure of PtCl(dcy)C6F5 shows near square planar stereochem. for platinum and steric congestion. The double bond from the six-membered ring of dcy is unsym. coordinated to platinum trans to C6F5 and is further from the metal than the other double bond, which is sym. bonded trans to chlorine. The pentafluorophenyl group is approx. normal to the coordination plane, and gives two o-fluorine resonances in the 19F NMR spectrum. In the experiment, the researchers used many compounds, for example, Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0HPLC of Formula: 12083-92-0).
Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.HPLC of Formula: 12083-92-0
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics