Kinetic and mechanistic consideration of the degradative oxidation of substituted mandelic acids by N-chlorosaccharin was written by Singh, V. P.;Khan, M. U.;Chauhan, D. B. S.;Verma, J. K.. And the article was included in Oxidation Communications in 1997.Application of 14070-51-0 This article mentions the following:
Kinetic data for the oxidation of p-chloro- and p-bromomandelic acids with N-chlorosaccharin (I) in aqueous AcOH were determined The reaction rate is a direct function of both [oxidant] and [substrate] in the lower concentration region, but tends toward zero order at higher substrate concentrations A retarding trend of H+ ions, solvent composition and saccharin on the system was observed The redox process proceeds via formation of an activated transition complex (1:1) between substrate and postulated HOCl reacting species of I, which slowly disintegrates into products. The oxidation products were confirmed, and a probable mechanism was suggested which was consistent with all observed kinetic results. In the experiment, the researchers used many compounds, for example, 2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide (cas: 14070-51-0Application of 14070-51-0).
2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide (cas: 14070-51-0) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Application of 14070-51-0
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics