Synthesis, Structure, and Reactivity of Iridium NHC Pincer Complexes was written by Schultz, Katherine M.;Goldberg, Karen I.;Gusev, Dmitry G.;Heinekey, D. Michael. And the article was included in Organometallics in 2011.SDS of cas: 39722-81-1 This article mentions the following:
Ir pincer complexes (C*C*CMes)IrCl2 (1), (C*C*CMes)IrH4 (2), and (C*C*CMes)Ir(H)2L (L = PMe3 (3), pyridine (4)) were prepared (C*C*C = [κ3-1,3-(CH2NHCMes)2C6H3]; NHCMes = N-mesitylimidazol-2-ylidene). Complexes 1–4 are the 1st examples of Ir complexes with C*C*C pincer ligands containing methylene bridges. Complex 2 activates C-H bonds of arenes at room temperature, as demonstrated by isotope exchange reactions. Under analogous conditions, no reaction was observed with alkanes. In the experiment, the researchers used many compounds, for example, Chlorobis(ethylene)iridium(I) dimer (cas: 39722-81-1SDS of cas: 39722-81-1).
Chlorobis(ethylene)iridium(I) dimer (cas: 39722-81-1) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.SDS of cas: 39722-81-1
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics