Tris(2,6-difluorophenyl)phosphite complexes of platinum group metals: structure of trans-PtCl2(PEt3){P(O-2,6-C6H3F2)3} was written by Coleman, Karl S.;Holloway, John H.;Hope, Eric G.;Russell, David R.;Saunders, Graham C.;Atherton, Malcolm J.. And the article was included in Polyhedron in 1995.HPLC of Formula: 39722-81-1 This article mentions the following:
The reactions between the F-containing ligand tris(2,6-difluorophenyl) phosphite and the transition metal species [{η6-1,4-CH3C6H4CHMe2}RuCl2]2, [Cp*RhCl2]2, [RhCl(CO)2]2, [PtCl2(PEt3)]2 and PtCl2 yield {η6-1,4-CH3C6H4CHMe2}RuCl2{P(O-2,6-C6H3F2)3}, Cp*RhCl2{P(O-2,6-C6H3F2)3}, trans-RhCl(CO){P(O-2,6-C6H3F2)3}2, trans-PtCl2(PEt3){P(O-2,6-C6H3F2)3} and trans-PtCl2{P(O-2,6-C6H3F2)3}2, resp. The mol. structure of trans-PtCl2(PEt3){P(O-2,6-C6H3F2)3} was determined by single-crystal x-ray crystallog. In the experiment, the researchers used many compounds, for example, Chlorobis(ethylene)iridium(I) dimer (cas: 39722-81-1HPLC of Formula: 39722-81-1).
Chlorobis(ethylene)iridium(I) dimer (cas: 39722-81-1) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.HPLC of Formula: 39722-81-1
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics