Reactions of aliphatic acetals with N-chlorosaccharin: a kinetic study was written by Basheer Ahamed, K. A.;Sheik Dawood, S.;Baskaran, P.;Nambi, K.. And the article was included in Journal of the Indian Chemical Society in 1996.Formula: C7H4ClNO3S This article mentions the following:
The title oxidation with excess acetals RCH(OR1)2 (I; R = Me, R1 = Et, Pr, Bu, Me2CHCH2, Me3C; R = ClCH2, CHCl2, Et, Pr, R1 = Et; R = Me, ClCH2, R1 = CH2Ph) in aqueous AcOH was 1st order in N-chlorosaccharin and zero order in I. The oxidation rate was enhanced by added H2SO4 or HClO4 but unaffected by added pyridine, and varied little with the structure of I. The rate-determining step thus involved dipolar rather than ionic species. In the experiment, the researchers used many compounds, for example, 2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide (cas: 14070-51-0Formula: C7H4ClNO3S).
2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide (cas: 14070-51-0) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. Alkyl chlorides readily react with amines to give substituted amines. Alkyl chlorides are substituted by softer halides such as the iodide in the Finkelstein reaction.Formula: C7H4ClNO3S
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics