Substrate-induced kinetic resolution of racemic diphosphines in situ for homogeneous catalysis was written by Alcock, Nathaniel W.;Brown, John M.;Maddox, Peter J.. And the article was included in Journal of the Chemical Society, Chemical Communications in 1986.Related Products of 39722-81-1 This article mentions the following:
The reaction between the resolved iridium enamide complexes I or II and chiral diphosphines was highly enantioselective and permitted their in situ resolution for asym. catalysis. The structure of I was confirmed by x-ray crystallog. In the experiment, the researchers used many compounds, for example, Chlorobis(ethylene)iridium(I) dimer (cas: 39722-81-1Related Products of 39722-81-1).
Chlorobis(ethylene)iridium(I) dimer (cas: 39722-81-1) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Related Products of 39722-81-1
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics