Gourdet, Benoit’s team published research in Tetrahedron in 66 | CAS: 480438-56-0

Tetrahedron published new progress about 480438-56-0. 480438-56-0 belongs to chlorides-buliding-blocks, auxiliary class Chloride,Boronic acid and ester,Benzene,Ether,Boronic Acids,Boronic acid and ester, name is 3-Chloro-4-isopropoxyphenylboronic acid, and the molecular formula is C9H12BClO3, Product Details of C9H12BClO3.

Gourdet, Benoit published the artcileRhodium-catalyzed carbometalation of ynamides with organoboron reagents, Product Details of C9H12BClO3, the publication is Tetrahedron (2010), 66(32), 6026-6031, database is CAplus.

In the presence of catalytic [Rh(cod)(MeCN)2]BF4, ynamides undergo carbometalation with boronic acids, arylboronic esters, and triarylboroxines. These reactions enable the regio- and stereocontrolled synthesis of multisubstituted enamides. E.g., reaction of 3-(2-phenylethynyl)oxazolidin-2-one with 4-chlorophenylboronic acid gave 65% 3-[(E)-2-(4-chlorophenyl)-2-phenylvinyl]oxazolidin-2-one (I).

Tetrahedron published new progress about 480438-56-0. 480438-56-0 belongs to chlorides-buliding-blocks, auxiliary class Chloride,Boronic acid and ester,Benzene,Ether,Boronic Acids,Boronic acid and ester, name is 3-Chloro-4-isopropoxyphenylboronic acid, and the molecular formula is C9H12BClO3, Product Details of C9H12BClO3.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics