Matheny, Jonathon P. published the artcileFacile assembly of 1,5-diazocan-2-ones via cyclization of tethered sulfonamides to cyclopropenes, SDS of cas: 21286-54-4, the publication is RSC Advances (2020), 10(72), 44183-44190, database is CAplus and MEDLINE.
The sulfonamide moiety was evaluated as an activating and stabilizing functional group in the metal-templated strain release-driven intramol. nucleophilic addition of amines to cyclopropenes to generate 1,5-diazocan-2-ones I [R = Me, 4-BrC6H4, 2-naphthyl, etc.].
RSC Advances published new progress about 21286-54-4. 21286-54-4 belongs to chlorides-buliding-blocks, auxiliary class Chiral,Chloride,Sulfonyl chlorides,Aliphatic cyclic hydrocarbon,Ketone, name is ((1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl)methanesulfonyl chloride, and the molecular formula is C10H15ClO3S, SDS of cas: 21286-54-4.
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