Veeresham, A. published the artcileGas chromatography/mass spectrometry analysis of reaction products of sulfur mustards with phenol, Application of 1,2-Bis(2-chloroethyl)disulfane, the publication is European Journal of Mass Spectrometry (2020), 26(3), 213-224, database is CAplus and MEDLINE.
Screening of chems. related to chem. weapons convention including their all possible degrdation and reaction products in environmental samples is important in the organization for prohibition of chem. weapons verification process. Sulfur mustards, commonly known as blistering agents, are included in schedule 1 chems. of chem. weapons convention. Because of the presence of chlorine atoms in sulfur mustards, they are highly reactive and prone to react with other organic mols. such as phenols to produce corresponding reaction products. In this study, the reaction products of the sulfur mustards with phenol (compounds 1-7) were studied by gas chromatog./mass spectrometry under electron ionization and chem. ionization conditions. The EI spectra of 1-7 displayed mol. ion and characteristic fragments that provided structure information. The methane or isobutane CI spectra showed M+., [M + H]+, and [M – H]+ ions including reagent specific adduct ions. The CI spectra also showed other adduct ions formed by association of analyte mols. with its most abundant fragment ion. The gas chromatog./retention index values were also calculated, which support unambiguous identification of targeted mols. in suspected environmental samples. The method was demonstrated for detection of the targeted mols. spiked in soil samples.
European Journal of Mass Spectrometry published new progress about 1002-41-1. 1002-41-1 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is 1,2-Bis(2-chloroethyl)disulfane, and the molecular formula is C7H7IN2O, Application of 1,2-Bis(2-chloroethyl)disulfane.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics