Prasad, G. K. published the artcileSun light assisted photocatalytic decontamination of sulfur mustard using ZnO nanoparticles, Application of 1,2-Bis(2-chloroethyl)disulfane, the publication is Journal of Molecular Catalysis A: Chemical (2011), 349(1-2), 55-62, database is CAplus.
Sunlight-assisted photocatalytic decontamination of sulfur mustard (HD) was studied using ZnO nanoparticles and the data were compared with those carried out in the presence of UVA and visible light radiation. In the presence of sunlight, 100% of HD was decomposed in 12 h. Whereas, in the presence of UVA light 90%, and in visible light 80% of HD was decomposed in 12 h. GC-MS data indicated the formation of thiodiglycol, hemisulfur mustard, divinyl sulfide, 2-chloro Et vinyl sulfide, etc., on the surface of ZnO nanoparticles in the case of dark and visible light irradiation experiments However, in sunlight and UVA light irradiation experiments, GC-MS data indicated the formation of HD sulfoxide, HD sulfone, 1,3-dithiane, 2-chloro ethanol, acetaldehyde, CO2, etc. along with hydrolysis and elimination products. Under the illumination of visible light and in dark hydrolysis, elimination and surface complexation reactions contributed to decontamination of HD. Whereas, in the presence of sunlight and UVA light, photocatalytic reactions like C-S bond cleavage, oxidation of C, S atoms were observed to have contributed to decontamination of HD in addition to hydrolysis and elimination reactions.
Journal of Molecular Catalysis A: Chemical published new progress about 1002-41-1. 1002-41-1 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is 1,2-Bis(2-chloroethyl)disulfane, and the molecular formula is C4H8Cl2S2, Application of 1,2-Bis(2-chloroethyl)disulfane.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics