Nevalainen, Vesa published the artcileStudies on the preparation of dihydro-1,4-oxathiines. Computer-assisted evaluation of the results of retrosynthetic analysis verified by synthetic experiments and by-product analyses. Synthetic pathways involving α-sulfenylated ketones and 1,3-oxathiolanes of α-halo and α-hydroxy ketones, COA of Formula: C4H8Cl2S2, the publication is Acta Chemica Scandinavica (1990), 44(6), 591-602, database is CAplus.
The preparation of 2- and 2,3-substituted 5,6-dihydro-1,4-oxathiines (I, R = Me or Ph, R1 = H, Me, CO2H, CO2Me, CO2Et, or CONHPh) was studied by computer simulation and by experiment Three major synthetic pathways, involving 2-(1-hydroxyalkyl)-1,3-oxathiolanes, 2-(1-haloalkyl)-1,3-oxathiolanes, 2-hydroxyethylthiomethyl ketones, methanesulfonates of 2-hydroxyethylthiomethyl ketones and 2-chloroethylthiomethyl ketones as intermediates, were evaluated, by running the program CAMEO, and by experiment The results of the two approaches were compared and the major byproducts of the reactions were identified by GLC/MS.
Acta Chemica Scandinavica published new progress about 1002-41-1. 1002-41-1 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is 1,2-Bis(2-chloroethyl)disulfane, and the molecular formula is C4H8Cl2S2, COA of Formula: C4H8Cl2S2.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics