Golubeva, E. N.’s team published research in Kinetics and Catalysis in 49 | CAS: 23616-79-7

Kinetics and Catalysis published new progress about 23616-79-7. 23616-79-7 belongs to chlorides-buliding-blocks, auxiliary class Phase Transfer Catalyst, name is N-Benzyl-N,N-dibutylbutan-1-aminium chloride, and the molecular formula is C19H34ClN, Formula: C19H34ClN.

Golubeva, E. N. published the artcileInfluence of the nuclearity of copper(II) chloride complexes on their activity in catalytic C-Cl bond metathesis, Formula: C19H34ClN, the publication is Kinetics and Catalysis (2008), 49(5), 737-742, database is CAplus.

Catalytic systems containing mainly mononuclear (CuCl42-) or dinuclear (Cu2Cl62-) tributylbenzylammonium chlorocuprates are prepared by adsorption on silica surfaces of different structures (Aerosil and Silokhrom). Using ESR, XANES, and electronic spectroscopy, the CuCl42- ions are shown to be reduced rapidly under conditions of C-Cl bond metathesis, whereas the dinuclear chlorocuprates are relatively stable. A correlation between the number of copper ions in the chlorocuprate anion and its catalytic activity is established: the mononuclear complexes are several times more active than their dinuclear counterparts.

Kinetics and Catalysis published new progress about 23616-79-7. 23616-79-7 belongs to chlorides-buliding-blocks, auxiliary class Phase Transfer Catalyst, name is N-Benzyl-N,N-dibutylbutan-1-aminium chloride, and the molecular formula is C19H34ClN, Formula: C19H34ClN.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics