Golubev, A. S. published the artcileSynthesis of 3-fluoromethyl-2,1-benzisoxazoles, Related Products of chlorides-buliding-blocks, the publication is Russian Chemical Bulletin (2014), 63(10), 2264-2270, database is CAplus.
A convenient synthetic method to access hitherto unknown 3-(trifluoromethyl)- and 3-(difluoromethyl)-2,1-benzisoxazoles by a reaction of sodium azide with 1-(2-halophenyl)-2,2,2-trifluoroethanone derivatives or 1-(2-halophenyl)-2,2-difluoroethanone derivatives was developed. 3-Fluoromethyl-2,1-benzisoxazoles are versatile precursors for o-(fluoroacetyl)aniline derivatives The synthesis of the target compounds was achieved by a reaction of sodium azide with 2,2,2-trifluoro-1-(2-fluorophenyl)ethanone 1-(2-chlorophenyl)-2,2,2-trifluoroethanone 1-(2,5-dichlorophenyl)-2,2,2-trifluoroethanone, 1-(5-bromo-2-fluorophenyl)-2,2,2-trifluoroethanone, 1-(2,5-dichlorophenyl)-2,2-difluoroethanone and 1-(5-bromo-2-fluorophenyl)-2,2-difluoroethanone. The formation of [2-(azido)phenyl]alkanone derivatives was postulated which underwent a cyclization reaction. The tilte compounds thus formed included 5-bromo-3-(trifluoromethyl)-1,2-benzisoxazole and similar compounds Ring-opening products included 1-(2-aminophenyl)-2,2,2-trifluoroethanone (aniline ketone, anthranil).
Russian Chemical Bulletin published new progress about 5860-95-7. 5860-95-7 belongs to chlorides-buliding-blocks, auxiliary class Trifluoromethyl,Fluoride,Chloride,Benzene,Ketone, name is 1-(2-Chlorophenyl)-2,2,2-trifluoroethanone, and the molecular formula is C8H4ClF3O, Related Products of chlorides-buliding-blocks.
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https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics