Doobary, Sayad published the artcileIntramolecular Alkene Fluoroarylation of Phenolic Ethers enabled by Electrochemically Generated Iodane, COA of Formula: C8H7ClO3, the publication is Journal of Organic Chemistry (2021), 86(22), 16095-16103, database is CAplus and MEDLINE.
Herein, synthesis of 3-fluorinated chromanes from allylic phenol ethers was described. Oxidant-free approach takes advantage of an electrochem. generation of a hypervalent iodine species, difluoro-λ3-tolyl iodane, which mediates the alkene fluoroarylation. High yields and selectivity for this transformation are achieved for electron poor substrates. The redox chem. has been characterized for the electrochem. generation of the iodane in the presence of fluoride, and insights into the mechanism are given. The transformation has been demonstrated on larger gram scales, which represents the potential broader utility of the process.
Journal of Organic Chemistry published new progress about 33697-81-3. 33697-81-3 belongs to chlorides-buliding-blocks, auxiliary class Chloride,Carboxylic acid,Benzene,Phenol, name is 3-Chloro-4-hydroxyphenylacetic acid, and the molecular formula is C8H7ClO3, COA of Formula: C8H7ClO3.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics