Cai, Xing-wei published the artcileLead/rare earth-free green-light-emitting crystal of molecular-based hybrid compound: (C5H13ClN)2[MnCl4] with large crystal size, COA of Formula: C5H13Cl2N, the publication is Wuji Huaxue Xuebao (2018), 34(2), 283-288, database is CAplus.
Reaction of MnCl2 and 2-dimethylaminoisopropyl chloride hydrochloride afforded one novel mol.-based material, (C5H13ClN)2[MnCl4] (1). And it is interesting to note that 1 exhibits intense greenish fluorescent emission (520 nm) at room temperature and relatively high thermal stability (stable up to 450 K). Moreover, structure and spectra analyses reveal that its excellent optical property can be attributed to the 4T1 (G) → 6A1 electronic transition of Mn2+ in [MnX4]2- tetrahedron.
Wuji Huaxue Xuebao published new progress about 4584-49-0. 4584-49-0 belongs to chlorides-buliding-blocks, auxiliary class Chloride,Salt,Amine,Aliphatic hydrocarbon chain, name is 2-Chloro-N,N-dimethylpropan-1-amine hydrochloride, and the molecular formula is C5H13Cl2N, COA of Formula: C5H13Cl2N.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics