Mangion, Ian K. published the artcileIridium-Catalyzed X-H Insertions of Sulfoxonium Ylides, Computed Properties of 5034-06-0, the publication is Organic Letters (2009), 11(16), 3566-3569, database is CAplus and MEDLINE.
The unique reactivity of sulfoxonium ylides as a carbene source is described for a variety of X-H bond insertions, taking advantage of a simple, com. available iridium catalyst. This method has applications in both intra- and intermol. reactivity, including a practical ring-expansion strategy for lactams. The safety and stability of sulfoxonium ylides recommend them as preferable surrogates to traditional diazo ketones and esters.
Organic Letters published new progress about 5034-06-0. 5034-06-0 belongs to chlorides-buliding-blocks, auxiliary class Salt,Aliphatic hydrocarbon chain, name is trimethyloxosulphonium chloride, and the molecular formula is C3H9ClOS, Computed Properties of 5034-06-0.
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