Li, Futing published the artcilePreparation of efficient and environment-friendly silica-supported EDTA platinum catalyst and its applications in hydrosilylation of olefins and methyldichlorosilane, HPLC of Formula: 14799-94-1, the publication is Journal of Molecular Catalysis A: Chemical (2016), 254-263, database is CAplus.
A novel catalyst by preparing silica supported EDTA (EDTA) platinum complex was developed. The preparation conditions, such as heating temperature and solvent types, were optimized. The catalyst was phosphine-free and sulfur-free which was characterized by IR spectroscopy (IR), energy dispersive X-ray spectrometer (EDS), transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM), XPS, UV spectroscopy (UV) and at. absorption spectroscopy (AAS). Its catalytic activity was evaluated by catalyzing solventless hydrosilylation reactions. In the hydrosilylation reaction between 1-hexene and methyldichlorosilane, the new catalyst showed a higher catalytic activity than that provided by Speier’s catalyst. Moreover, the new catalyst could be reused for 12 times without obvious loss of catalytic activity. To confirm its practical feasibility, catalyzing the hydrosilylation reaction between 1-octene and methyldichlorosilane was performed. Our results indicated that the new catalyst can efficiently catalyze the hydrosilylation reaction.
Journal of Molecular Catalysis A: Chemical published new progress about 14799-94-1. 14799-94-1 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Dichloro(hexyl)(methyl)silane, and the molecular formula is C7H16Cl2Si, HPLC of Formula: 14799-94-1.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics