Arthuis, Martin published the artcilePd0-Catalyzed carbonylation of 1,1-dichloro-1-alkenes, a new selective access to Z-α-chloroacrylates, HPLC of Formula: 866-23-9, the publication is Chemical Communications (Cambridge, United Kingdom) (2010), 46(41), 7810-7812, database is CAplus and MEDLINE.
A novel and fully chemo- and stereoselective three component strategy leading to Z-α-chloroacrylates by a Pd0-catalyzed reaction of CO (1 atm) with 1,1-dichloro-1-alkenes and various alcs. is disclosed. This catalytic approach compares favorably with the Wittig type strategies as α-chloroacrylates of pure Z configuration are obtained in high yield.
Chemical Communications (Cambridge, United Kingdom) published new progress about 866-23-9. 866-23-9 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Diethyltrichloromethylphosphonate, and the molecular formula is C5H10Cl3O3P, HPLC of Formula: 866-23-9.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics