Suzuki, Nobutaka published the artcilePhotochemical type I and II elimination reactions of dialkyl (trichloromethyl)phosphonates, Computed Properties of 866-23-9, the publication is Bulletin of the Chemical Society of Japan (1980), 53(5), 1421-4, database is CAplus.
Irradiation of CCl3P(O)(OR)2 (I; R = Et, Pr, CH2CHMe2) in MeCN gave the corresponding monoesters and olefins via photochem. type-II elimination. In addition, products via type-I elimination were obtained from I (R = Me, CH2CHMe2).
Bulletin of the Chemical Society of Japan published new progress about 866-23-9. 866-23-9 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Diethyltrichloromethylphosphonate, and the molecular formula is C5H6BNO2, Computed Properties of 866-23-9.
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