Martyanov, Igor N. published the artcilePhotocatalytic Oxidation of Gaseous 2-Chloroethyl Ethyl Sulfide over TiO2, Recommanded Product: 1,2-Bis(2-chloroethyl)disulfane, the publication is Environmental Science and Technology (2003), 37(15), 3448-3453, database is CAplus and MEDLINE.
Photocatalytic oxidation of gaseous 2-chloroethyl Et sulfide (2-CEES) over TiO2 illuminated with UV light and maintained at 25° or 80° in air has been investigated. 2-CEES was found to suffer progressive oxidation to yield ethylene, chloroethylene, ethanol, acetaldehyde, chloroacetaldehyde, di-Et disulfide, 2-chloroethyl Et disulfide, and bis(2-chloroethyl) disulfide as the main primary intermediates, and water, carbon dioxide, sulfur dioxide, surface sulfate ions, and hydrogen chloride as the final products. Trace concentrations of gaseous 2-chloroethanol, ethanesulfonyl chloride, Et thioacetate, and considerable amounts of acetic acid, crotonaldehyde, Me acetate, and Me formate were also detected in the gas phase during the photooxidation conducted at 80°. An increase in temperature from 25° to 80° accelerates formation of gaseous ethanol, acetaldehyde, chloroacetaldehyde, di-Et disulfide, 2-chloroethyl Et disulfide, and bis(2-chloroethyl) disulfide but suppresses ethylene and chloroethylene production at initial stages of the process. Some aspects of the possible reaction mechanism leading to this wide array of intermediates and final products are discussed.
Environmental Science and Technology published new progress about 1002-41-1. 1002-41-1 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is 1,2-Bis(2-chloroethyl)disulfane, and the molecular formula is C4H8Cl2S2, Recommanded Product: 1,2-Bis(2-chloroethyl)disulfane.
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