Brode, Wallace R. published the artcileRearrangement of the isomeric 1,2-(dimethylamino)-chloropropanes. The synthesis of amidone, Related Products of chlorides-buliding-blocks, the publication is Journal of the American Chemical Society (1947), 724, database is CAplus and MEDLINE.
Chlorination of MeCH(OH)CH2NMe2 (I) (b. 124-4.5°) and MeCH(NMe2)CH2OH (II) (b. 145-5.5°) with SOCl2 in anhydrous CHCl3 yields MeCHClCH2NMe2.HCl (III) and MeCH(NMe2)CH2Cl.HCl (IV), resp.; IV is much more soluble in CHCl3 than III. IV and III and a mixture of the 2 all m. 191-1.5°, indicating rearrangement to the same compound on heating. The free base from III or IV b110 60-3°; with Ag2O it gives 12% II.
Journal of the American Chemical Society published new progress about 4584-49-0. 4584-49-0 belongs to chlorides-buliding-blocks, auxiliary class Chloride,Salt,Amine,Aliphatic hydrocarbon chain, name is 2-Chloro-N,N-dimethylpropan-1-amine hydrochloride, and the molecular formula is C5H13Cl2N, Related Products of chlorides-buliding-blocks.
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