Methylene chain ruler for evaluating the regioselectivity of a substrate-recognizing oxidation catalyst was written by Teramae, Shota;Kito, Akane;Shingaki, Tomoteru;Hamaguchi, Yu;Yano, Yuuki;Nakayama, Takamori;Kobayashi, Yuko;Kato, Nobuki;Umezawa, Naoki;Hisamatsu, Yosuke;Nagano, Tetsuo;Higuchi, Tsunehiko. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2019.SDS of cas: 6294-17-3 The following contents are mentioned in the article:
Regioselective C-H oxidation of aliphatic mols. with synthetic catalysts is challenging. The authors incorporated substrate-recognition sites into a Ru porphyrin-heteroaromatic N-oxide catalytic system to characterize its regioselectivity for the oxidation of alkanes. This substrate-recognition catalytic reaction exhibits high regioselectivity and high reaction efficiency. This study involved multiple reactions and reactants, such as 1-Bromo-6-chlorohexane (cas: 6294-17-3SDS of cas: 6294-17-3).
1-Bromo-6-chlorohexane (cas: 6294-17-3) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. Alkyl chlorides readily react with amines to give substituted amines. Alkyl chlorides are substituted by softer halides such as the iodide in the Finkelstein reaction.SDS of cas: 6294-17-3
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics