Alkayal, Nazeeha’s team published research in Polymer Chemistry in 6 | CAS: 5034-06-0

Alkayal, Nazeeha published the artcileWell-defined polymethylene-based block co/terpolymers by combining anthracene/maleimide Diels-Alder reaction with polyhomologation, Category: chlorides-buliding-blocks, the publication is Polymer Chemistry (2015), 6(27), 4921-4926, database is CAplus.

A novel strategy towards well-defined polymethylene-based co/terpolymers, by combining the anthracene/maleimide Diels-Alder reaction with polyhomologation, is presented. For the synthesis of diblock copolymers the following approach was applied: (a) synthesis of α-anthracene-ω-hydroxy-polymethylene by polyhomologation using tri(9-anthracene-Me Pr ether)borane as the initiator, (b) synthesis of furan-protected-maleimide-terminated poly(ε-caprolactone) or polyethylene glycol and (c) the Diels-Alder reaction between the anthracene and maleimide-terminated polymers. In the case of triblock terpolymers the α-anthracene-ω-hydroxy-polymethylene was used as a macroinitiator for the ring-opening polymerization of D, L – lactide to afford an anthracene-terminated PM-b-PLA copolymer, followed by the Diels-Alder reaction with furan-protected maleimide-terminated poly (ε-caprolactone) or polyethylene glycol to give the triblock terpolymers. All the intermediates and final products were characterized by SEC, ¹H NMR, UV-VIS spectroscopy and DSC.

Polymer Chemistry published new progress about 5034-06-0. 5034-06-0 belongs to chlorides-buliding-blocks, auxiliary class Salt,Aliphatic hydrocarbon chain, name is trimethyloxosulphonium chloride, and the molecular formula is C3H9ClOS, Category: chlorides-buliding-blocks.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics