Tan, Guangying published the artcileRhodium-Catalyzed Dealkenylative Arylation of Alkenes with Arylboronic Compounds, SDS of cas: 145349-62-8, the publication is Angewandte Chemie, International Edition (2021), 60(28), 15650-15655, database is CAplus and MEDLINE.
Herein, the first example of rhodium-catalyzed dealkenylative arylation of alkenes with arylboronic compounds, thereby providing an unconventional access to biaryls with excellent chemoselectivity was diclosed. In this method, C(aryl)-C(alkenyl) and C(alkenyl)-C(alkenyl) bonds in various alkenes and 1,3-dienes could be cleaved via a hydrometalation and followed by β-carbon elimination pathway for Suzuki-Miyaura reactions. Furthermore, a series of novel organic fluorescent mols. with excellent photophys. properties were efficiently constructed with this protocol.
Angewandte Chemie, International Edition published new progress about 145349-62-8. 145349-62-8 belongs to chlorides-buliding-blocks, auxiliary class Chloride,Boronic acid and ester,Benzene,Boronic Acids, name is 2-Chloro-4-methylphenylboronic acid, and the molecular formula is C6H4KNO6S, SDS of cas: 145349-62-8.
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https://en.wikipedia.org/wiki/Chloride,
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