Raja, K. Kanmani published the artcileSynthesis, spectral, electrochemical and catalytic properties of Cu(II), Ni(II) and Co(II) complexes containing N,O donors, Computed Properties of 19652-33-6, the publication is Journal of Molecular Catalysis A: Chemical (2009), 303(1-2), 52-59, database is CAplus.
Metal(II) chelates of Schiff bases derived from the condensation of multi-substituted aniline with salicylaldehyde derivatives were prepared Product structures were determined by NMR, IR, EPR, magnetic and cyclic voltammetry measurements. The complexes are of the type M(X-DPMP)2 [(M = Cu(II), Ni(II) or Co(II)), DPMP = 2-[[(2,6-diisopropylphenyl)imino]methyl]phenol, X = Br, Cl, I, BrCl]. These Schiff bases behave as monobasic bidentate ligands in their complexes. The spectral data indicate that the ligand coordinates through a phenolic oxygen and the azomethine nitrogen atoms. The observed A || values in the Cu(II) complexes indicate a tetrahedrally distorted square planar structure. The cyclic voltammetric redox potential of copper(II) and nickel(II) complexes suggest the existence of irreversible pairs in acetonitrile. Cu(Br-DPMP)2 was found to be an efficient catalyst for the cyanosilylation of aldehydes under mild conditions.
Journal of Molecular Catalysis A: Chemical published new progress about 19652-33-6. 19652-33-6 belongs to chlorides-buliding-blocks, auxiliary class Chloride,Bromide,Benzene,Phenol,Aldehyde, name is 5-Bromo-3-chloro-2-hydroxybenzaldehyde, and the molecular formula is C7H4BrClO2, Computed Properties of 19652-33-6.
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https://en.wikipedia.org/wiki/Chloride,
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