Liu, Xing published the artcileChemoselective Chan-Lam Coupling Reactions between Benzimidazoline-2-thiones and Arylboronic Acids, Product Details of C7H8BClO2, the publication is Journal of Organic Chemistry (2019), 84(18), 11524-11532, database is CAplus and MEDLINE.
An efficient Chan-Lam-type methodol. for the selective synthesis of S-arylbenzimidazoles and N,S-diarylbenzimidazoles was developed. The selectivity was controlled by varying the amount of the catalyst Cu(OAc)2·H2O, temperature, and solvent switching. These transformations feature a simple protocol, broad functional group tolerance, high selectivity, and good to excellent yields. It is noteworthy that these reactions represent the first examples of the application of the selective Chan-Lam coupling.
Journal of Organic Chemistry published new progress about 145349-62-8. 145349-62-8 belongs to chlorides-buliding-blocks, auxiliary class Chloride,Boronic acid and ester,Benzene,Boronic Acids, name is 2-Chloro-4-methylphenylboronic acid, and the molecular formula is C7H8BClO2, Product Details of C7H8BClO2.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
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