Leggio, Antonella published the artcileUnusual Reactivity of Dimethylsulfoxonium Methylide with Esters, HPLC of Formula: 5034-06-0, the publication is European Journal of Organic Chemistry (2012), 2012(1), 114-118, database is CAplus.
Dimethylsulfoxonium methylide was treated with esters under mild conditions to rapidly afford the corresponding carboxylic acids at room temperature Moreover, by performing the procedure on enantiopure substrates, it was demonstrated that the reaction occurs without racemization. 18O-labeled reagents showed that the reaction does not proceed through an ester hydrolysis mechanism. The reactions are characterized by an unusual reactivity of the dimethylsulfoxonium methylide. This methodol. is general and can be considered a valid alternate route for ester cleavage when a substrate is sensitive to hydrolysis conditions.
European Journal of Organic Chemistry published new progress about 5034-06-0. 5034-06-0 belongs to chlorides-buliding-blocks, auxiliary class Salt,Aliphatic hydrocarbon chain, name is trimethyloxosulphonium chloride, and the molecular formula is C3H9ClOS, HPLC of Formula: 5034-06-0.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics