Application of the e-NRTL model to electrolytes in mixed solvents methanol-, ethanol- water, and PEG-water was written by Valverde, J. L.;Ferro, V. R.;Giroir-Fendler, A.. And the article was included in Fluid Phase Equilibria in 2022.Electric Literature of ClLi The following contents are mentioned in the article:
In this work, the e-NRTL binary interaction parameters for the alc.-water (ethanol-water and methanol-water), electrolyte-alc. (NaBr-methanol, NaBr-ethanol, NaCl-methanol, NaCl-ethanol, KCl-methanol and KCl-ethanol), PEG (polyethylene glycol)-water (PEG1000-, PEG4000- and PEG6000-water) and electrolyte-PEG (NaCl and KCl-PEG4000-water, KCl-PEG1000-water, LiCl-PEG4000-Water, CsCl-PEG (PEG1000, PEG4000 and PEG 6000)-Water) were evaluated by the non-linear regression of exptl. data at different temperatures, reported in the literature. The application used was able to evaluate the impact of the NRTL, Debye-Huckel and Born contributions on the activity coefficients of a salt (or an electrolyte) in different media. In addition, the solubility constants, and the free energy of transfer on the molar scale of NaCl, KCl and NaBr in alc.-water mixed solvents (methanol-water and ethanol-water at different temperatures) were evaluated by using the e-NRTL model and the binary interaction parameters previously computed. It was reached an excellent correlation of the exptl. data of water activity, mean activity coefficient and osmotic pressure data of ethanol-water and methanol-water solutions, electrolyte-alc. systems, and electrolyte-PEG, resp. The presence of PEG and alc. in solution had a great influence on the solubility of the solid phases. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Electric Literature of ClLi).
Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.Electric Literature of ClLi
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics