Ultrafast dynamics of ionic liquids in colloidal dispersion was written by Ren, Zhe;Kelly, Jordan;Gunathilaka, C. Prasad;Brinzer, Thomas;Dutta, Samrat;Johnson, Clinton A.;Mitra, Sunayana;Garrett-Roe, Sean. And the article was included in Physical Chemistry Chemical Physics in 2017.Application In Synthesis of N-Benzyl-N,N-dimethylhexadecan-1-aminium chloride The following contents are mentioned in the article:
Ionic liquid (IL)-surfactant complexes have significance both in applications and fundamental research, but their underlying dynamics are not well understood. The authors apply polarization-controlled two-dimensional IR spectroscopy (2D-IR) to study the dynamics of [BMIM][SCN]/surfactant/solvent model systems. The authors examine the effect of the choice of surfactants and solvent, and the IL-to-surfactant ratio (W-value), with a detailed anal. of the orientation and structural dynamics of each system. Different surfactants create very different environments for the entrapped ILs, ranging from a semi-static micro-environment to a fluxional environment that evolves even faster than the bulk IL. The oil-phase also clearly affects the microscopic dynamics. The anisotropy decay for entrapped ILs completes within 10 ps, which is similar to free thiocyanate ion in water, while a significant reorientation-induced spectral diffusion (RISD) effect is observed The entrapped ionic liquid are highly dynamic for all W-values, and no core-shell structure is observed Authors hypothesize that, instead of an ionic liquid-reverse micelle (IL-RM), the microscopic structure of this system is small colloidal dispersions or pairs of IL and surfactants. A detailed anal. of the polarization-controlled 2D-IR spectra of AOT system reveals a potential ion-exchange mechanism. This study involved multiple reactions and reactants, such as N-Benzyl-N,N-dimethylhexadecan-1-aminium chloride (cas: 122-18-9Application In Synthesis of N-Benzyl-N,N-dimethylhexadecan-1-aminium chloride).
N-Benzyl-N,N-dimethylhexadecan-1-aminium chloride (cas: 122-18-9) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Application In Synthesis of N-Benzyl-N,N-dimethylhexadecan-1-aminium chloride
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics