Thermodynamic assessment of lithium halide reciprocal salt systems for energy applications was written by Aziziha, Mina;Schorne-Pinto, Juliano;Yingling, Jacob A.;Dixon, Clara M.;Ard, Johnathan C.;A. A. Aslani, Mahmoud;Mofrad, Amir M.;Besmann, Theodore M.. And the article was included in Journal of Molecular Liquids in 2022.Application In Synthesis of Lithium chloride The following contents are mentioned in the article:
Lithium halides are of interest because of their unique applications as fuel or coolants in molten salt reactors (MSRs) and electrolytes in thermally activated batteries. Because iodine is an important fission product for MSRs, the molten salt thermal properties database-Thermochem. (MSTDB-TC) is being expanded to include relevant iodide reciprocal salt systems. In this work, we assess the thermochem. properties of lithium halide pseudobinary systems based on reported exptl. phase diagrams, eutectic temperatures, and enthalpies of mixing. Within the framework of the modified quasi-chem. model in the quadruplet approximation (MQMQA), extrapolations to the related pseudoternary and pseudoquaternary systems have been performed. The pseudoquaternary representations of phase equilibrium, enthalpy, entropy, and heat capacity are represented in the resultant models. Of interest for generating source terms for accident anal. is the ability to compute the vapor pressures of the dominant iodide species for the systems at any composition An example of such calculations is provided for the LiF-LiI system at xLiI = 0.01 and xLiI = 0.70, in this case indicating that the LiI vapor species are predominant. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Application In Synthesis of Lithium chloride).
Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Application In Synthesis of Lithium chloride
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics