Synthesis, characterization, antibacterial, anticancer, and density-functional theory studies of nano-metal(II) oxime complexes was written by Al-Sabawi, Emad N.;Al-Janabi, Ahmed S. M.;Jerjis, Haifa Muhammed;Khairy, Mohammed;Alduaij, Omar K.;Yousef, Tarek A.. And the article was included in Applied Organometallic Chemistry in 2022.Application In Synthesis of Sodium tetrachloropalladate(II) The following contents are mentioned in the article:
New nanophenolic oxime complexes of the type [M(κ2-Saly)2] {where HSaly = salicyl-aldoxime; M = Co (1), Ni (2), Cu (3), Pd (4), Pt (5), Zn (6), Cd (7), and Hg (8)} were prepared and characterized by different spectroscopic methods. The surface morphol. and the micrographs of the investigated complexes were checked by the SEM and x-ray diffraction (XRD) anal. The results indicate the successful preparation of nanocomplexes with nanoparticles size. In addition, the antibacterial activity was studied against three different pathogenic bacteria, and the Pt(II) complex displayed the highest activity compared with free salicylaldoxime ligand and other complexes. Magnetic susceptibility and UV-visible spectroscopic measurements were used to deduce the geometry of the complexes, which was then validated by d. functional theory (DFT) calculations The in vitro antitumor activity was investigated by MTT assays against HepG-2 cell lines. The Zn(II) and Pt(II) complexes displayed good activity with IC50 values at 17.31 ± 0.95 and 11.78 ± 0.54μM, resp. In contrast, the [Cu(Saly)2] and [Ni(Saly)2] complexes showed the lowest activity against tested cells. This study involved multiple reactions and reactants, such as Sodium tetrachloropalladate(II) (cas: 13820-53-6Application In Synthesis of Sodium tetrachloropalladate(II)).
Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Application In Synthesis of Sodium tetrachloropalladate(II)
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics