Synthesis and studies on S-triazine-based ligand and its metal complexes was written by Shanmugakala, R.;Tharmaraj, P.;Sheela, C. D.;Anitha, C.. And the article was included in International Journal of Inorganic Chemistry in 2012.Synthetic Route of C9H6Cl2N4 The following contents are mentioned in the article:
Tridentate chelate complexes of ML type (where M = Cu(II), Ni(II), and Co(II)) have been synthesized from triazine-based ligand 4,6-bis(5-mercapto-1,3,4-thiadiazol-amine)2-phenylamino-1,3,5-triazine (BMTDT). Microanal. data, magnetic susceptibility measurements, IR, 1H NMR, UV-vis, mass, and EPR spectral techniques were used to characterize the structure of chelates. The electronic absorption spectra and magnetic susceptibility measurements suggest that metal complexes show square pyramidal geometry. The electrochem. behavior of copper(II) complex is studied by cyclic voltammetry. All synthesized compounds may serve as potential photoactive materials as indicated from their characteristic fluorescence properties. The second harmonic generation efficiency (SHG) of the ligand and metal complexes has been found to be higher than that of urea and KDP. The antimicrobial activity of the ligand and metal(II) complexes against the species Shigella, Chromobacterium, Staphylococcus aureus, Candida albicans, and Aspergillus niger has been carried out and compared with the standard one. This study involved multiple reactions and reactants, such as 4,6-Dichloro-N-phenyl-1,3,5-triazin-2-amine (cas: 2272-40-4Synthetic Route of C9H6Cl2N4).
4,6-Dichloro-N-phenyl-1,3,5-triazin-2-amine (cas: 2272-40-4) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.Synthetic Route of C9H6Cl2N4
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics