Understanding the Chemical Shifts of Aqueous Electrolyte Species Adsorbed in Carbon Nanopores was written by Sasikumar, Anagha;Griffin, John M.;Merlet, Celine. And the article was included in Journal of Physical Chemistry Letters in 2022.Related Products of 7447-41-8 The following contents are mentioned in the article:
Interfaces between aqueous electrolytes and nanoporous carbons are involved in a number of technol. applications such as energy storage and capacitive deionization. Nuclear magnetic spectroscopy is a very useful tool to characterize ion adsorption in such systems thanks to its nuclei specificity and the ability to distinguish between ions in the bulk and in pores. We use complementary methods (d. functional theory, mol. dynamics simulations and a mesoscopic model) to investigate the relative importance of various effects on the chem. shifts of adsorbed species: ring currents, ion organization in pores of various sizes, specific ion-carbon interactions and hydration. We show that ring currents and ion organization are predominant for the determination of chem. shifts in the case of Li+ ions and hydrogen atoms of water. For the large Rb+ and Cs+ ions, the addnl. effect of the hydration shell should be considered to predict chem. shifts in agreement with experiments This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Related Products of 7447-41-8).
Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. Alkyl chlorides readily react with amines to give substituted amines. Alkyl chlorides are substituted by softer halides such as the iodide in the Finkelstein reaction.Related Products of 7447-41-8
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics