Novel (100-x-y)Li3PS4-xLiBF4-yLiCl amorphous solid electrolytes for all-solid-state Li ion battery was written by Phuc, Nguyen H. H.;Gamo, H.;Hikima, K.;Muto, H.;Matsuda, A.. And the article was included in Journal of Non-Crystalline Solids in 2022.Application of 7447-41-8 The following contents are mentioned in the article:
Amorphous solid electrolytes in the composition (100-x-y)Li3PS4-xLiBF4-yLiCl (x, y: mol%) were prepared using the high-energy ball-milling method. XRD, FT-IR, and solid-state 31P NMR proved the formation of amorphous samples. Peak shifting in FT-IR spectra illustrated the dissociation of LiBF4 and LiCl. Solid-state 31P NMR demonstrated the formation of highly distorted PS4 tetrahedral. Those structural characteristics accompanied by elec. conductivity enhancement from 2.8 x 10-4 Scm-1 of Li3PS4 to 6.3 x 10-4 Scm-1 in 50Li3PS4·40LiBF4·10LiCl solid electrolyte. Besides elec. conductivity, electrochem. stability against Li metal and LiNi0.5Co0.2Mn0.3O2, operated at high voltage, was also achieved with the existence of LiBF4 and LiCl in solid electrolytes. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Application of 7447-41-8).
Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Application of 7447-41-8
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics