Trialkylmethylammonium molybdate ionic liquids as novel oil-soluble precursors of dispersed metal catalysts for slurry-phase hydrocracking of heavy oils was written by Ma, Yongde;Zhang, Jiayin;Wu, Wenquan;Cai, Zhenping;Cao, Yanning;Huang, Kuan;Jiang, Lilong. And the article was included in Chemical Engineering Science in 2022.Product Details of 5137-55-3 The following contents are mentioned in the article:
Slurry-phase hydrocracking is an effective technol. for the conversion of heavy oils to clean and light fuels. Herein, trialkylmethylammonium molybdate ionic liquids (ILs) with multiple long-chain alkyl groups were designed, and applied as the oil-soluble precursors of dispersed metal catalysts for slurry-phase hydrocracking. The molybdate ILs were synthesized through a two- or three-step route from readily available reagents under mild conditions. The chem. structure and sulfidation behavior of molybdate ILs were characterized first. The performance of molybdate ILs for hydrogenation was then evaluated with phenanthrene as the model compound The dispersed MoS2 catalysts in-situ produced in the model system were isolated and characterized to explain the different performance of oil-soluble precursors. The performance of molybdate ILs for slurry-phase hydrocracking of heavy oils was finally investigated. To figure out the favored routes for the conversion of heavy oils, the reaction rate constants were also calculated based on an established kinetical model. This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3Product Details of 5137-55-3).
N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Product Details of 5137-55-3
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics