Tungsten ion complexes in cationic/anionic molten salt system: thermodynamic/dynamic/simulation investigation reveals configuration-induced changes in reaction was written by Feng, Ming;Xi, Xiao-li;Zhang, Li-wen;Nie, Zuo-ren. And the article was included in Journal of Physical Chemistry C in 2022.SDS of cas: 7447-41-8 The following contents are mentioned in the article:
The macroscopic properties of reactions are closely tied not only to the thermodn. and dynamics of the reactions but also to the microstructure of the ionic complexes. We herein report the anal. of the reduction process of tungsten ions in molten salt by combining the electrochem., thermodn., dynamic, and configuration parameters. The thermodn. and dynamic properties, including the apparent electrode potential, Gibbs free energy, and diffusion coefficient, of the tungsten ions were calculated by square-wave voltammetry and were found to be in good agreement with the simulation results. In addition, the concomitant changes of the diffusion coefficient and coordination number are elucidated. In all cases, the change of coordination number of the tungsten ion complexes led to the change of electrochem., thermodn., and dynamic parameters. These findings propose a new dimension for regulating the structure of metal ion complexes and analyzing the reaction properties. The combination of simulation and experiment provides a basis for the mechanism anal. of the reduction and synthesis of metal materials. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8SDS of cas: 7447-41-8).
Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.SDS of cas: 7447-41-8
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics