Heterogeneous asymmetric passable cavities within graphene oxide nanochannels for highly efficient lithium sieving was written by Ahmadi, Hadi;Zakertabrizi, Mohammad;Hosseini, Ehsan;Cha-Umpong, Withita;Abdollahzadeh, Mojtaba;Korayem, Asghar Habibnejad;Chen, Vicki;Shon, Ho Kyong;Asadnia, Mohsen;Razmjou, Amir. And the article was included in Desalination in 2022.Synthetic Route of ClLi The following contents are mentioned in the article:
Lithium is a critical energy element that plays a pivotal role in transitions to sustainable energy. Numerous two-dimensional (2D) membranes have been developed to extract Li+ from different resources. However, their Li+ extraction efficacy is not high enough to meet industrial requirements. Here, we introduce an approach that boosts Li+ selectivity of 2D membranes by inducing asymmetricity in the morphol. and chem. of their nanochannels. Our approach provides an opportunity to manipulate cation hydration shells via a sudden change in the nanochannel size. Then, the addition of nucleophilic traps in the nanochannel intersections results in high Li+ selectivity. Our design leads to a new ion transport mechanism named “Energy Surge Baffle” (ESB) that substantially enriches Li+ in the feed by increasing the monovalent/lithium-ion selectivity up to six times that of other graphene oxide-based membranes. Our approach can be extended to other 2D materials, creating a platform for designing advanced membranes. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Synthetic Route of ClLi).
Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Synthetic Route of ClLi
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics