In-situ Raman investigation and application of phenazine-based organic electrode in aqueous proton batteries was written by Shi, Minjie;He, Jing;Zhao, Yue;Zhao, Liping;Dai, Kun;Yan, Chao. And the article was included in Materials & Design in 2022.Safety of Lithium chloride The following contents are mentioned in the article:
Aqueous proton batteries (APBs) have aroused attention because of the proton as charge carrier with smaller ionic size and faster kinetics when compared to the metallic ions in aqueous solutions Although phenazine-based organic compounds with available redox-active sites are considered as promising organic electrode materials, the comprehensive study of their proton-storage behaviors and APB applications is still lacking so far. Herein, a rod-like diquinoxalino-phenazine (DPZ) organic compound is designed and synthesized via a facile dehydration approach. In-situ Raman investigation and theor. calculation are conducted to probe into the proton redox process of DPZ organic electrode for the first time. It is demonstrated that three C=N electroactive regions in each DPZ mol. unit could be simultaneously coordinated with two protons and the redox reaction between C=N and C-N bonds is highly reversible upon proton insertion/extraction As expected, the DPZ organic electrode delivers a large proton-storage capacity of ∼ 218 mAh/g and long-term cycle performance without obvious dissoly. in acidic aqueous electrolyte. For real applications, soft-package and wire-shaped APBs based on such DPZ organic electrode are constructed, and they both achieve outstanding electrochem. characteristics, revealing their great potential applications in low-cost, high-safety, and high-performance energy technologies and portable/wearable electronics. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Safety of Lithium chloride).
Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.Safety of Lithium chloride
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics