How the type of interface can alter the behavior of an aprotic ionic liquid-water mixture entrapped in different reverse micelles: An exploratory study using an enzymatic reaction as a sensor was written by Blach, Diana;Girardi, Valeria R.;Silber, Juana J.;Correa, N. Mariano;Falcone, R. Dario. And the article was included in Colloids and Surfaces, A: Physicochemical and Engineering Aspects in 2022.Electric Literature of C25H46ClN The following contents are mentioned in the article:
In this work, we decipher how an aprotic Ionic Liquid (IL)-water mixture structure can be altered upon confinement in different reverse micelles (RMs) media. Thus, the effect of the polar pseudophase composition in RMs formulated by anionic or cationic surfactants was monitored using the well-known enzymic hydrolysis reaction of 1-naphthyl phosphate (1-NP) with alk. phosphatase (AP). Water and an aqueous mixture formed by the IL 1-butyl-3-methylimidazolium trifluoromethanesulfonate ([C4C1i.m., TfO]) as the polar pseudophase were used. As surfactants, the anionic sodium diethylhexyl sulfosuccinate (AOT) and the cationic benzyl-n-hexadecyldimethylammonium chloride (BHDC) were employed. The effect of the nanoconfinement, as well as the impact of the polar solvent content and the type of interface, were analyzed by determining the Michaelis-Menten parameters. In homogeneous media, the catalytic efficiency of the hydrolysis reaction is strongly dependent on the amount of water in the mixtures evaluated. In RMs the catalytic efficiency is dependent on both, the polar content and the type of surfactant used. Thus, by using a model reaction with an enzyme entrapped inside different RMs it was possible to learn that an aprotic IL:water mixture can be strongly disturbed when it is confined in a cationic or anionic RMs. This particular behavior can produce a deep impact on the technol. applications of these organized systems. This study involved multiple reactions and reactants, such as N-Benzyl-N,N-dimethylhexadecan-1-aminium chloride (cas: 122-18-9Electric Literature of C25H46ClN).
N-Benzyl-N,N-dimethylhexadecan-1-aminium chloride (cas: 122-18-9) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.Electric Literature of C25H46ClN
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics